\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)

\(n_{HCl}=2,5.0,2=0,5mol\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

0,2  <  0,5                            ( mol )

0,2      0,4            0,2         0,2     ( mol )

Chất dư là HCl

\(m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65g\)

\(V_{H_2}=0,2.22,4=4,48l\)

\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,2}=1M\)

`n_[Fe]=[11,2]/56=0,2(mol)`

`n_[HCl]=0,3.2=0,6(mol)`

`Fe + 2HCl -> FeCl_2 + H_2 \uparrow`

`0,2`   `0,4`             `0,2`     `0,2`         `(mol)`

`a)` Ta có:`[0,2]/1 < [0,6]/2`

    `=>HCl` dư

`=>V_[H_2]=0,2.22,4=4,48(l)`

`b)HCl` còn dư sau p/ứ

`=>m_[HCl(dư)]=(0,6-0,4).36,5=7,3(g)`

`c)C_[M_[FeCl_2]]=[0,2]/[0,3]~~0,67(M)`

  `C_[M_[HCl(dư)]=[0,6-0,4]/[0,3]~~0,67(M)`

\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

\(n_{HCl}=0,3.2=0,6\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

0,2 <    0,6                        ( mol )

0,2       0,4          0,2        0,2      ( mol )

\(V_{H_2}=0,2.22,4=4,48\left(l\right)\)

Chất dư là HCl

\(m_{HCl\left(dư\right)}=\left(0,6-0,4\right).36,5=7,3\left(g\right)\)

\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,3}=0,66\left(M\right)\)

\(C_{M_{HCl\left(dư\right)}}=\dfrac{0,2}{0,3}=0,66\left(M\right)\)

1.

n_Al=\(\dfrac{5,4}{27}\)=0,2 mol

m_HCl=\(\dfrac{175.14,6}{100}\)=25,55g

n_HCl=\(\dfrac{25,55}{36,5}\)=0,7

                     2Al + 6HCl → 2AlCl₃ + 3H₂↑

n trước pứ    0,2     0,7  

n pứ              0,2 →0,6  →    0,2  →  0,3  mol

n sau pứ       hết   dư 0,1

Sau pứ HCl dư.

m_HCl (dư)= 36,5.0,1=3,65g

m_{các chất sau pư}= 5,4 +175 - 0,3.2= 179,8g

m_AlCl3= 133,5.0,2=26,7g

C%_ddHCl (dư)= \(\dfrac{3,65.100}{179,8}=2,03%\)%

C%_ddAlCl3 = \(\dfrac{26,7.100}{179,8}\)= 14,85%

2.

           200ml= 0,2l

m_Mg= \(\dfrac{4,2}{24}=0,175mol\)

    Mg + 2HCl → MgCl₂ + H₂↑

0,175→ 0,35 → 0,175→0,175 mol

a) V_H2= 0,175.22,4=3,92l.

b)C%_dHCl= \(\dfrac{0,35}{0,2}=1,75\)M

a) PTHH: \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\uparrow\)

Ta có: \(\left\{{}\begin{matrix}n_{BaCO_3}=\dfrac{68,95}{197}=0,35\left(mol\right)\\n_{HCl}=0,25\cdot3,2=0,8\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,35}{1}< \dfrac{0,8}{2}\) \(\Rightarrow\) Axit còn dư 

\(\Rightarrow n_{HCl\left(dư\right)}=0,8-0,35\cdot2=0,1\left(mol\right)\) \(\Rightarrow m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\)

b+c) Theo PTHH: \(\left\{{}\begin{matrix}n_{CO_2}=n_{BaCl_2}=0,35\left(mol\right)\\n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{CO_2}=0,35\cdot22,4=7,84\left(l\right)\\C_{M_{BaCl_2}}=\dfrac{0,35}{0,25}=1,4\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,25}=0,4\left(M\right)\end{matrix}\right.\) 

\(300(ml)=0,3(l)\\ n_{HCl}=1.0,3=0,3(mol);n_{Fe}=\dfrac{5,6}{56}=0,1(mol)\\ a,PTHH:Fe+2HCl\to FeCl_2+H_2\\ \text{LTL: }\dfrac{n_{Fe}}{1}<\dfrac{n_{HCl}}{2}\Rightarrow HCl\text{ dư}\\ \Rightarrow n_{HCl(dư)}=0,3-0,1.2=0,1(mol)\\ \Rightarrow m_{HCl(dư)}=0,1.36,5=3,65(g)\\ b,n_{FeCl_2}=n_{Fe}=0,1(mol)\\ \Rightarrow \begin{cases} C_{M_{FeCl_2}}=\dfrac{0,1}{0,3}=0,33M\\ C_{M_{HCl(dư)}}=\dfrac{0,1}{0,3}=0,33M \end{cases}\)

Ta có: \(n_{MgO}=\dfrac{4}{40}=0,1\left(mol\right)\)

\(n_{HCl}=4.100:1000=0,4\left(mol\right)\)

a. PTHH: MgO + 2HCl ---> MgCl₂ + H₂O

Ta thấy: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\)

Vậy HCl dư.

=> \(n_{dư}=\dfrac{0,1.2}{0,4}=0,5\left(mol\right)\)

=> \(m_{dư}=0,5.36,5=18,2\left(g\right)\) 

b. Ta có: \(V_{dd_{MgCl_2}}=V_{HCl}=\dfrac{100}{1000}=0,1\left(lít\right)\)

Theo PT: \(n_{MgCl_2}=n_{MgO}=0,1\left(mol\right)\)

=> \(C_{M_{MgCl_2}}=\dfrac{0,1}{0,1}=1M\)

\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

\(n_{HCl}=0,1.1=0,1\left(mol\right)\)

PTHH : 

              \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Trc p/u:  0,1      0,1          

p/u :       0,05     0,1         0,05       0,05 

Sau p/u :  0,05    0            0,05       0,05 

-> Fe dư sau p/u 

a) \(m_{H_2}=0,05.2=0,1\left(g\right)\)

b) sau p/ư Fe dư 

 \(m_{Fedư}=0,05.2,8\left(g\right)\)

c) \(m_{FeCl_2}=0,05.\left(56+35,5.2\right)=6,35\left(g\right)\)

PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)

a) Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot4,9\%}{98}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Cả 2 chất p/ứ hết

b+c) Theo PTHH: \(n_{ZnSO_4}=n_{H_2}=n_{Zn}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}m_{ZnSO_4}=0,1\cdot161=16,1\left(g\right)\\m_{H_2}=0,1\cdot2=0,2\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Zn}+m_{ddH_2SO_4}-m_{H_2}=206,3\left(g\right)\)

\(\Rightarrow C\%_{ZnSO_4}=\dfrac{16,1}{206,3}\cdot100\%\approx7,8\%\)

a, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

\(n_{H_2SO_4}=0,2.2=0,4\left(mol\right)\)

PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,4}{1}\), ta được H₂SO₄ dư.

Theo PT: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)

b, - H₂SO₄ dư.

\(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,2=0,2\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,2.98=19,6\left(g\right)\)

c, \(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,2}{0,2}=1\left(M\right)\)

Theo PT: \(n_{FeSO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,2}{0,2}=1\left(M\right)\)